| 12.01.2022 20:00 | Panathinaikos | 74 : 98 | CSKA Moscow |
| 12.01.2022 21:30 | Partizan | 97 : 65 | Dolomiti Energia Trento | |
| 12.01.2022 21:00 | Joventut | 100 : 77 | Lokomotiv Kuban | |
| 12.01.2022 19:00 | Lietkabelis | 96 : 89 | Metropolitans 92 |
| 12.01.2022 20:30 | Ratiopharm Ulm | 70 : 76 | Valencia | |
| 12.01.2022 20:00 | Budućnost VOLI | 83 : 82 | Frutti Extra Bursaspor | |
| 12.01.2022 20:30 | Virtus Segafredo | 83 : 82 | Mincidelice JL Bourg Basket |
| 12.01.2022 16:30 | Kraljevo | 102 : 99 | Art Basket |
| 12.01.2022 18:00 | Hajduk Veljko | 56 : 62 | Svrljig |
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